934550
Silyl-ether based ROMP monomer
iPrSi
Synonym(e):
2,2-Bis(1-methylethyl)-1,3-dioxa-2-silacyclohept-5-ene
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About This Item
Empirische Formel (Hill-System):
C11H22O2Si
CAS-Nummer:
Molekulargewicht:
214.38
MDL-Nummer:
UNSPSC-Code:
12162002
NACRES:
NA.21
Empfohlene Produkte
Assay
≥98%
Qualitätsniveau
Form
liquid
Zusammensetzung
iPrSi
Farbe
colorless to pale yellow
Lagertemp.
2-8°C
SMILES String
CC(C)[Si]1(C(C)C)OC/C=C\CCO1
Allgemeine Beschreibung
Ring opening metathesis polymerization (ROMP) monomers are attractive building block for advanced polymeric materials in the biomedical field. 2,2-Bis(1-methylethyl)-1,3-dioxa-2-silacyclohept-5-ene , or the silyl ether based ROMP monomer iPrSi, is a bifunctional cyclic olefin that can be used to synthesize a variety of marcomolecules and polymers with diverse compositions and complex structures. iPrSi can copolymerize with a variety of norbornene derivatives including small molecules and macromolecules, enabling the formation of backbone-degradable copolymers that can be used in a variety of biomedical applications. The ROMP polymerization method is superior as it permits the tailorability of the resulting polymer material.
Anwendung
Synthesis of advanced polymeric materials for biomedical applications including:
- drug delivery
- molecular imaging
- self assembly
- hydrogels
- medical device coatings
- stimuli responsive material
Leistungsmerkmale und Vorteile
- Copolymerize efficiency with a wide variety of norbornene-based (macro)monomers
- Controlled ROMP polymerization
- Silyl ether substitute can be tuned to control degradation
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Produkt-Nr.
Beschreibung
Preisangaben
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Analysenzertifikate (COA)
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Scott C Radzinski et al.
Macromolecular rapid communications, 37(7), 616-621 (2016-02-06)
Bottlebrush polymers are synthesized using a tandem ring-opening polymerization (ROP) and ring-opening metathesis polymerization (ROMP) strategy. For the first time, ROP and ROMP are conducted sequentially in the same pot to yield well-defined bottlebrush polymers with molecular weights in excess
Peyton Shieh et al.
Nature chemistry, 11(12), 1124-1132 (2019-10-30)
Ring-opening metathesis polymerization of norbornene-based (macro)monomers is a powerful approach for the synthesis of macromolecules with diverse compositions and complex architectures. Nevertheless, a fundamental limitation of polymers prepared by this strategy is their lack of facile degradability, limiting their utility
Banruo Huang et al.
Journal of the American Chemical Society, 143(43), 17920-17925 (2021-10-23)
Materials capable of degradation upon exposure to light hold promise in a diverse range of applications including biomedical devices and smart coatings. Despite the rapid access to macromolecules with diverse compositions and architectures enabled by ring-opening metathesis polymerization (ROMP), a
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