928305

cataCXium^® A Pd G3 ChemBeads

• Synonym(e): Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
• Empirische Formel (Hill-System): C₃₇H₅₂NO₃PPdS
• CAS-Nummer: 1651823-59-4
• Molekulargewicht: 728.27
• UNSPSC-Code: 12352101
• NACRES: NA.82

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Zusammensetzung: ~ 4 wt.% loading of catalyst
• Eignung der Reaktion: reagent type: catalyst; reaction type: Cross Couplings

Beschreibung

Anwendung

cataCXium^® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

• Direct ortho-arylation of pyridinecarboxylic acids.
• Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
• Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
• Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

Sonstige Hinweise

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

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ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Rechtliche Hinweise

cataCXium is a registered trademark of Umicore AG & Co. KG

Sicherheitshinweise

• Piktogramme: GHS08
• Signalwort: Danger
• H-Sätze: H350i
• P-Sätze: P201 - P202 - P280 - P308 + P313 - P405 - P501
• Gefahreneinstufungen: Carc. 1B Inhalation
• Lagerklassenschlüssel: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 3