67873

4-Methyl-morpholin-4-oxid Monohydrat

≥95.0% (N)

• Synonym(e): 4-Methylmorpholine 4-oxide monohydrate, 4-Methylmorpholine oxide monohydrate, N-Methylmorpholine N-oxide monohydrate, N-Methylmorpholine oxide monohydrate
• Empirische Formel (Hill-System): C₅H₁₁NO₂ · H₂O
• CAS-Nummer: 70187-32-5
• Molekulargewicht: 135.16
• Beilstein: 507437
• EG-Nummer: 231-391-8
• MDL-Nummer: MFCD00149388
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 57652112
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥95.0% (N)
• mp (Schmelzpunkt): 71-75 °C
• Funktionelle Gruppe: ether
• SMILES String: O.C[N+]1([O-])CCOCC1
• InChI: 1S/C5H11NO2.H2O/c1-6(7)2-4-8-5-3-6;/h2-5H2,1H3;1H2
• InChIKey: WAZPLXZGZWWXDQ-UHFFFAOYSA-N

Beschreibung

Anwendung

4-Methylmorpholine N-oxide (MNO) monohydrate can be used:

• As a reagent in the dihydroxylation and aminohydroxylation of olefins in the presence of osmium tetroxide (OsO₄) catalyst.
• In the selective oxidation of sulphides to sulfoxides or sulfones in the presence of manganese and copper complexes with tetradentate ligands.

Sonstige Hinweise

Reagent for an improved catalytic OsO₄ oxidation of olefins to cis-1,2-diols; Review; For a ruthenium catalysed oxidation of alcohols to aldehydes and ketones

Sicherheitshinweise

• Piktogramme: GHS08
• Signalwort: Warning
• H-Sätze: H361f
• P-Sätze: P201 - P202 - P280 - P308 + P313 - P405 - P501
• Gefahreneinstufungen: Repr. 2
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 1
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves