673978

2,6-Bis[(3aS,8aR)-3a,8a-Dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridin

• Synonym(e): (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridindiyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazol, (3aS,8aR)-in-pybox
• Empirische Formel (Hill-System): C₂₅H₁₉N₃O₂
• CAS-Nummer: 185346-09-2
• Molekulargewicht: 393.44
• MDL-Nummer: MFCD05861599
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329760573
• NACRES: NA.22

Eigenschaften

• Form: solid
• Optische Aktivität: [α]20/D -375°, c = 1 in dichloromethane (typical)
• mp (Schmelzpunkt): 276-281 °C
• Funktionelle Gruppe: ether
• SMILES String: C1[C@H]2OC(=N[C@H]2c3ccccc13)c4cccc(n4)C5=N[C@@H]6[C@@H](Cc7ccccc67)O5
• InChI: 1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1
• InChIKey: BZSJUFJXCHHRHW-LUKWVAJMSA-N

Beschreibung

Anwendung

Reactant involved in synthesis of:

• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
• Chiral N,N,N-tridentate pybos and pyboxazine ligands

Sicherheitshinweise

• H-Sätze: H413
• Gefahreneinstufungen: Aquatic Chronic 4
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable