Direkt zum Inhalt
Merck
Alle Fotos(1)

Key Documents

View All Documentation

672661

Sigma-Aldrich

2-(Di-tert.-butyl-phosphino)-1-phenyl-1H-pyrrol

95%

Synonym(e):

cataCXium® PtB

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(1)

About This Item

Empirische Formel (Hill-System):
C18H26NP
CAS-Nummer:
672937-61-0
Molekulargewicht:
287.38
Beilstein:
9626114
MDL-Nummer:
MFCD05861612
UNSPSC-Code:
12352005
PubChem Substanz-ID:
329760523
NACRES:
NA.22

Assay

95%

Eignung der Reaktion

reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Dehydrogenation
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

Funktionelle Gruppe

phosphine

SMILES String

CC(C)(C)P(c1cccn1-c2ccccc2)C(C)(C)C

InChI

1S/C18H26NP/c1-17(2,3)20(18(4,5)6)16-13-10-14-19(16)15-11-8-7-9-12-15/h7-14H,1-6H3

InChIKey

DVVDGSKDQGMLPW-UHFFFAOYSA-N

Allgemeine Beschreibung

Verkauf in Zusammenarbeit mit Solvias AG

Rechtliche Hinweise

WO 2004/101581
cataCXium is a registered trademark of Umicore AG & Co. KG

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
BCCC8211
BCBW1589
BCBR3582V
BCBG9860V
BCBB8327V

Die passende Version wird nicht angezeigt?

Wenn Sie eine bestimmte Version benötigen, können Sie anhand der Lot- oder Chargennummer nach einem spezifischen Zertifikat suchen.

Suche nach COA

Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Cen Tang et al.
ACS nano, 14(9), 11605-11612 (2020-09-01)
The capping reagent plays an essential role in the functional properties of gold nanoparticles (AuNPs). Multiple stimuli-responsive materials are generated via diverse surface modification. The ability of the organic ligand shell on a gold surface to create a porous shell
Hai T Dong et al.
Inorganic chemistry, 59(20), 14967-14982 (2020-09-30)
We previously reported the synthesis and preliminary characterization of a unique series of low-spin (ls) {FeNO}8-10 complexes supported by an ambiphilic trisphosphineborane ligand, [Fe(TPB)(NO)]+/0/-. Herein, we use advanced spectroscopic techniques and density functional theory (DFT) calculations to extract detailed information
Michelle Muñoz-Osses et al.
Dalton transactions (Cambridge, England : 2003), 47(39), 13861-13869 (2018-09-19)
Cyrhetrenyl aldehyde derivatives [(η5-C5H4CHO)Re(CO)2PR3] with R = methyl (Me, 2a), phenyl (Ph, 2b), and cyclohexyl (Cy, 2c) were synthesized by a photochemical reaction from the starting material [(η5-C5H4CHO)Re(CO)3] (1) and the corresponding phosphines. The complexes were fully characterized by FT-IR
Xi Kang et al.
Chemical Society reviews, 49(17), 6443-6514 (2020-08-08)
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles, providing unique opportunities for investigating the quantum effects and precise structure-property correlations at the atomic level. As a versatile strategy, alloying can largely improve the physicochemical performances compared to
Grant E Johnson et al.
Physical chemistry chemical physics : PCCP, 17(22), 14636-14646 (2015-05-15)
We present a systematic study of the effect of the number of methyl (Me) and cyclohexyl (Cy) functional groups in monodentate phosphine ligands on the solution-phase synthesis of ligated sub-nanometer gold clusters and their gas-phase fragmentation pathways. Small mixed ligand

Artikel

cataCXium

cataCXium® - Ligands and Complexes for Efficient Cross-Coupling Reactions. Cross-coupling reactions are an important class of catalytic transformations with applications in polymer science as well as in the fine chemicals and pharmaceutical industries.

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

Setzen Sie sich mit dem technischen Dienst in Verbindung.