671800

Di-(1-adamantyl)-benzylphosphin

95%

• Synonym(e): cataCXium^® ABn
• Empirische Formel (Hill-System): C₂₇H₃₇P
• CAS-Nummer: 395116-70-8
• Molekulargewicht: 392.56
• Beilstein: 9359745
• MDL-Nummer: MFCD05861603
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 329760443
• NACRES: NA.22

Eigenschaften

• Assay: 95%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Asymmetric synthesis
• Funktionelle Gruppe: phosphine
• SMILES String: C1[C@H]2C[C@H]3C[C@@H]1C[C@@](C2)(C3)P(Cc4ccccc4)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
• InChI: 1S/C27H37P/c1-2-4-19(5-3-1)18-28(26-12-20-6-21(13-26)8-22(7-20)14-26)27-15-23-9-24(16-27)11-25(10-23)17-27/h1-5,20-25H,6-18H2/t20-,21+,22-,23-,24+,25-,26-,27-
• InChIKey: ANIAFEJRWQDKDV-ANIFQACUSA-N

Beschreibung

Allgemeine Beschreibung

Verkauf in Zusammenarbeit mit Solvias AG

Anwendung

Catalyst for:

• Sonogashira coupling reaction
• Ruthenium-catalyzed amination of secondary alcohols. with ammonia
• Rhodium-catalyzed regioselective hydroformylation of alkenes
• Reductive carbonylation
• Suzuki coupling reaction

Rechtliche Hinweise

US7148176

cataCXium is a registered trademark of Umicore AG & Co. KG

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)