640360

Bis(acetonitril)(1,5-cyclooctadien)rhodium(I)tetrafluoroborat

• Synonym(e): [Rh(cod)(MeCN)₂]BF₄
• Empirische Formel (Hill-System): C₁₂H₁₈BF₄N₂Rh
• CAS-Nummer: 32679-02-0
• Molekulargewicht: 379.99
• MDL-Nummer: MFCD06798085
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24883086
• NACRES: NA.22

Eigenschaften

• Form: solid
• Eignung der Reaktion: core: rhodium; reagent type: catalyst
• SMILES String: [Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
• InChI: 1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
• InChIKey: KSMAFOANQHYEJG-SUESZSCISA-N

Beschreibung

Anwendung

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)₂]BF₄ may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves