547980

Tris[N,N-bis(trimethylsilyl)amid]samarium(III)

98%

• Synonym(e): 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
• Lineare Formel: Sm(N(Si(CH₃)₃)₂)₃
• CAS-Nummer: 35789-01-6
• Molekulargewicht: 631.51
• MDL-Nummer: MFCD03427097
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24879000
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: solid
• Eignung der Reaktion: core: samarium; reagent type: catalyst
• mp (Schmelzpunkt): 93-106 °C (lit.)
• SMILES String: C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Sm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChIKey: MUFPZLRACJKLCI-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for synthesis of:

• Heterobimetallic samarium(III) complexes
• Binuclear lanthanide complexes

Catalyst for:

• Coordination polymerization of renewable butyrolactone-based vinyl monomers
• Intramolecular hydroamination of non-activated alkenes
• Chiral functionalization of isoxazoles
• Enantioselective hydroamination / cyclization

Sicherheitshinweise

• Piktogramme: GHS02,GHS05
• Signalwort: Danger
• H-Sätze: H228,H261,H314
• P-Sätze: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 36.0 °F - closed cup
• Flammpunkt (°C): 2.2 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges