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Merck

497355

Sigma-Aldrich

Calciumhydrid

greener alternative

powder, 99.99% trace metals basis

Synonym(e):

Calcium dihydride

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About This Item

Empirische Formel (Hill-System):
H2Ca
CAS-Nummer:
Molekulargewicht:
42.09
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.23

Assay

99.99% trace metals basis

Form

powder

Eignung der Reaktion

reagent type: reductant

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp (Schmelzpunkt)

816 °C (lit.)

Grünere Alternativprodukt-Kategorie

SMILES String

[Ca]

InChI

1S/Ca.2H

InChIKey

FAQLAUHZSGTTLN-UHFFFAOYSA-N

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Allgemeine Beschreibung

2 g packaged in glass bottles; 10 g packaged in steel cans
The crystal structure of calcium hydride is a slightly distorted hexagonal close packing. At elevated temperatures, calcium hydride acts as a strong reducing agent.1 Solid state reaction between hexachlorobenzene and calcium hydride has been studied in detail.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Calcium hydride (CaH2) is a metal hydride that can be used for a variety of greener applications such as:
  • fabrication of hydrogen storage systems for fuel cell applications
  • synthesis of porous aromatic frameworks (PAFs) for adsorption of organic pollutants
  • formation of high temperature superconductors

Calcium hydride is widely used as a drying agent for organic solvents.1 It has been used to dry ε-caprolactone,benzene and toluene.

Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - Water-react 1

Lagerklassenschlüssel

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

The crystal structure of calcium hydride.
Bergsma J and Loopstra BO
Acta Crystallographica, 15(1), 92-93 (1962)
Reversible hydrogen storage in the lithium borohydride?calcium hydride coupled system
Pinkerton FE and Meyer MS
Journal of alloys and compounds, 464(1-2), L1-L4 (2008)
Synthesis of a porous aromatic framework for adsorbing organic pollutants application
Ren H, et al.
Journal of Materials Chemistry, 21(28), 10348-10353 (2011)
The mechanochemical self-propagating reaction between hexachlorobenzene and calcium hydride.
Mulas G, et al.
Journal of Solid State Chemistry, 129(2), 263-270 (1997)
Sang Cheon Lee et al.
Journal of controlled release : official journal of the Controlled Release Society, 89(3), 437-446 (2003-05-10)
Polymeric micelles based on amphiphilic block copolymers of poly(2-ethyl-2-oxazoline) (PEtOz) and poly(epsilon -caprolactone) (PCL) were prepared in an aqueous phase. The loading of paclitaxel into PEtOz-PCL micelles was confirmed by 1H-NMR spectra. Paclitaxel was efficiently loaded into PEtOz-PCL micelles using

Artikel

Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids

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