425508

2,6-Dimethylphenylmagnesiumbromid -Lösung

1.0 M in THF

• Synonym(e): 2,6-Xylylmagnesium bromide, Bromo(2,6-dimethylphenyl)magnesium
• Lineare Formel: (CH₃)₂C₆H₃MgBr
• CAS-Nummer: 21450-64-6
• Molekulargewicht: 209.37
• MDL-Nummer: MFCD00192083
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24866639
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 1.0 M in THF
• bp: 65-67 °C
• Dichte: 0.998 g/mL at 25 °C
• SMILES String: Cc1cccc(C)c1[Mg]Br
• InChI: 1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
• InChIKey: BIGUVDUZGAJWQK-UHFFFAOYSA-M

Beschreibung

Anwendung

2,6-Dimethylphenylmagnesium bromide can be used:

• As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
• As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS08,GHS05
• Signalwort: Danger
• H-Sätze: H225,H261,H302,H314,H331,H335,H351
• P-Sätze: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): -2.2 °F - closed cup
• Flammpunkt (°C): -19 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter