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Methylpipecolinat -hydrochlorid
97%
Synonym(e):
Methyl 2-piperidinecarboxylate hydrochloride
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About This Item
Empirische Formel (Hill-System):
C7H13NO2 · HCl
CAS-Nummer:
Molekulargewicht:
179.64
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
97%
mp (Schmelzpunkt)
205 °C (dec.) (lit.)
Funktionelle Gruppe
ester
SMILES String
Cl.COC(=O)C1CCCCN1
InChI
1S/C7H13NO2.ClH/c1-10-7(9)6-4-2-3-5-8-6;/h6,8H,2-5H2,1H3;1H
InChIKey
APCHKWZTSCBBJX-UHFFFAOYSA-N
Allgemeine Beschreibung
Methyl pipecolinate hydrochloride is a hydrochloride salt of methyl piperidine-2-carboxylate (methyl pipecolinate). The kinetics of the enzymatic separation of enantiomeric forms of methyl pipecolinate using Candida antarctica Lipase A (CAL-A) has been reported. Its role as catalyst for the standard Diels-Alder reaction has been examined.
Anwendung
Reactant for synthesis of:
A pipecolic linker
Antiviral agents
Aurora and epidermal growth factor receptor kinase inhibitor
Pyrrolidine derivatives via reduction of substituted pyrroles
Reactant for:
Petasis reactions
Decarbonylative radical cyclization of alpha-amino selenoesters upon electrophilic alkenes
A pipecolic linker
Antiviral agents
Aurora and epidermal growth factor receptor kinase inhibitor
Pyrrolidine derivatives via reduction of substituted pyrroles
Reactant for:
Petasis reactions
Decarbonylative radical cyclization of alpha-amino selenoesters upon electrophilic alkenes
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Advances in the kinetic and dynamic kinetic resolution of piperazine-2-carboxylic acid derivatives with Candida antarctica lipase A; structural requirements for enantioselective N-acylation.
Hietanen A, et al.
ARKIVOC (Gainesville, FL, United States), 5, 60-74 (2012)
Aldehyde-based racemization in the dynamic kinetic resolution of N-heterocyclic a-amino esters using Candida Antarctica lipase A.
Liljeblad A, et al.
Tetrahedron, 60(3), 671-677 (2004)
The α-effect in cyclic secondary amines: new scaffolds for iminium ion accelerated transformations.
Brazier JB, et al.
Tetrahedron, 65(48), 9961-9966 (2009)
Enantioselective lipase-catalyzed reactions of methyl pipecolinate: transesterification and N-acylation.
Liljeblad, A, et al.
Tetrahedron Letters, 43(13), 2471-2474 (2002)
Alkoxycarbonylpiperidines as N-nucleophiles in the palladium-catalyzed aminocarbonylation.
Takacs A, et al.
Monatshefte fur Chemie / Chemical Monthly, 145(9), 1473-1478 (2014)
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