360058

(Triphenylsilyl)acetylen

98%

• Synonym(e): 1,1′,1′′-(Ethynylsilylidyne)tris[benzene], Ethynyltriphenylsilane, Triphenylsilylacetylene, Triphenylsilylethyne
• Lineare Formel: (C₆H₅)₃SiC≡CH
• CAS-Nummer: 6229-00-1
• Molekulargewicht: 284.43
• MDL-Nummer: MFCD00075453
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24862140
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• mp (Schmelzpunkt): 48-50 °C (lit.)
• SMILES String: C#C[Si](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C20H16Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h1,3-17H
• InChIKey: WADKYPSVXRWORK-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

(Triphenylsilyl)acetylene is a terminal alkyne. Rhodium-catalyzed asymmetric addition of (triphenylsilyl)acetylene to diphenylphosphinylallene is reported.

Anwendung

(Triphenylsilyl)acetylene may be used in the synthesis of:

• selenothioic acid S-alkyl esters
• methyl 2-(di{ 3, 5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoate
• 2-(di{3,5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoic acid

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves