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Documentos Principais

CRM69091

Supelco

Dinotefuran

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Sinônimo(s):

(RS)-N-Methyl-N′-nitro-N″-[(tetrahydro-3-furanyl)methyl]guanidine

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About This Item

Fórmula empírica (Notação de Hill):
C7H14N4O3
Número CAS:
Peso molecular:
202.21
Número MDL:
Código UNSPSC:
41116107
NACRES:
NA.24

grau

certified reference material
TraceCERT®

Nível de qualidade

linha de produto

TraceCERT®

prazo de validade

limited shelf life, expiry date on the label

fabricante/nome comercial

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

formato

neat

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CN\C(N[N+]([O-])=O)=N/CC1CCOC1

InChI

1S/C7H14N4O3/c1-8-7(10-11(12)13)9-4-6-2-3-14-5-6/h6H,2-5H2,1H3,(H2,8,9,10)

chave InChI

YKBZOVFACRVRJN-UHFFFAOYSA-N

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Descrição geral

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Dinotefuran is a third-generation chiral neonicotinoid insecticide, used against sucking, biting, and public health insects such as mosquitoes, ticks, beetles, aphids, whiteflies, and leaf hoppers. It disrupts the insect nervous system by exhibiting agonistic activity towards the nicotinic acetylcholine (ACh) receptors (nAChR) and affecting the cholinergic synaptic transmission.
Under the Regulation (EC) No 1107/2009 and revoking the Council Directives 79/117/EEC and 91/414/EEC, dinotefuran is not approved for its use as a plant protection agent in the European Union (EU). But a default maximum residue limit (MRL) of 0.01 mg/kg is set for dinotefuran in accordance with Art 18(1)(b) Reg 396/2005.

Aplicação

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The dinotefuran CRM may also find given below uses:
  • Development of a method to simultaneously determine dinotefuran and its 3 polar metabolites in plum samples using dispersive-solid phase extraction procedure (d-SPE) followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Potentiometric determination of dinotefuran residues in soil and cucumber samples by using novel molecularly imprinted polymeric (MIP) material based sensors
  • Evaluation of an ultra high-performance liquid chromatography-tandem triple quadrupole mass spectrometry based method for the detection and quantification of dinotefuran and its metabolites in products of plant (watermelon, cucumber, rice) and animal (milk, egg, and pork) origin and also environmental samples of soil and water
  • Multi-residue analysis of pyridaben, dinotefuran, and metabolites of dinotefuran in soil and eggplant samples with a modified QuEChERS based sample extraction and rapid resolution liquid chromatography-triple quadrupole-tandem mass spectrometry (RRLC-QqQ-MS/MS)
  • Quantitative analysis of dinotefuran and its two metabolites in rice plant samples by high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS)
  • Development of a method to determine residues of dinotefuran and its two major metabolites in apple samples by QuEChERS based sample pre-treatment and liquid chromatography-tandem mass spectrometry (LC-MS/MS)

Informações legais

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Eye Irrit. 2

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Xiaoxin Chen et al.
Chemosphere, 195, 245-251 (2017-12-23)
A sensitive method for simultaneous determination of pyridaben, dinotefuran, DN and UF in eggplant ecosystem was established and validated through rapid resolution liquid chromatography triples quadrupole tandem mass spectrometry (RRLC-QqQ-MS/MS). Matrix-matched external calibrations were introduced to check matrix effects. Limits
Md Musfiqur Rahman et al.
Food chemistry, 239, 1235-1243 (2017-09-07)
A simple and effective method was developed for analyzing dinotefuran and its three metabolites (MNG, UF, and DN) in plum using liquid chromatography-tandem mass spectrometry (LC-MS/MS). Due to the polarity and high water miscibility, dinotefuran and some of its metabolites
Zenglong Chen et al.
Environment international, 130, 104854-104854 (2019-06-15)
In last decade, there has been a concerted effort to reduce the potential threats of honeybees' population due to exposure to neonicotinoid pesticides. A new perspective was put forward to reduce the potential ecological toxicity of neonicotinoid dinotefuran to honeybee

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