CRM44794

Phosphamidon

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Sinônimo(s): 2-Chloro-N,N-diethyl-3-(dimethylphosphono)crotonic amide
• Fórmula empírica (Notação de Hill): C₁₀H₁₉ClNO₅P
• Número CAS: 13171-21-6
• Peso molecular: 299.69
• Beilstein: 8323501
• Número MDL: MFCD00055301
• Código UNSPSC: 41116107
• NACRES: NA.24

Propriedades

• grau: certified reference material; TraceCERT^®
• Nível de qualidade: 300
• linha de produto: TraceCERT^®
• prazo de validade: limited shelf life, expiry date on the label
• fabricante/nome comercial: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• Formato: neat
• temperatura de armazenamento: −20°C
• cadeia de caracteres SMILES: CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC
• InChI: 1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+
• chave InChI: RGCLLPNLLBQHPF-CMDGGOBGSA-N

Descrição

Descrição geral

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.

Aplicação

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:

• Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
• Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
• Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
• Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
• Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
• Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus

Informações legais

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Informações de segurança

• Pictogramas: GHS06,GHS08,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H300,H311,H341,H410
• Declarações de precaução: P202 - P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312
• Classificações de perigo: Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2
• Código de classe de armazenamento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable