940356

GPhos Pd G3 ChemBeads

• Sinônimo(s): Methanesulfonato[Dicyclohexyl[3-(1,1-dimethylethoxy)-6-methoxy-2′,6′-bis(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine](2′-amino-1,1′-biphenyl-2-yl)palladium(II) ChemBeads
• Fórmula empírica (Notação de Hill): C₄₈H₆₆NO₅PPdS
• Número CAS: 2489525-82-6
• Peso molecular: 906.50
• Código UNSPSC: 12352100

Propriedades

• forma: solid
• Nível de qualidade: 100
• composição: , 4-6 wt. % (loading)
• adequação da reação: reagent type: catalyst
• cadeia de caracteres SMILES: O=S(O[Pd]([P](C1CCCCC1)(C2CCCCC2)C3=C(C4=C(C(C)C)C=CC=C4C(C)C)C(OC)=CC=C3OC(C)(C)C)C5=C(C6=C(N)C=CC=C6)C=CC=C5)(C)=O
• InChI: InChI=1S/C35H53O2P.C12H10N.CH4O3S.Pd/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15,20-27H,9-14,16-19H2,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• chave InChI: PLMOFCQYSAAMKA-UHFFFAOYSA-M

Descrição

Descrição geral

The ChemBeads product of the GPhos ligand combined with the Buchwald third Generation Palladacycle. The GPhos motif gives superb activity while having greater stability relative to other superbulky Buchwald ligands. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE). GPhos Pd G3 has been used in: - The production of chiral N-arylamines via a telescoped transaminase-Buchwald-Hartwig Amination cascade.

Aplicação

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical. For general uses, product is also available in powdered form (920460 )

Características e benefícios

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3