756741

PCy3 Pd G2

95%

• Sinônimo(s): Chloro[(tricyclohexylphosphine)-2-(2′-aminobiphenyl)]palladium(II), Tricyclohexylphosphine Pd G2
• Fórmula empírica (Notação de Hill): C₃₀H₄₃ClNPPd
• Número CAS: 1353658-81-7
• Peso molecular: 590.52
• Número MDL: MFCD21363051
• Código UNSPSC: 12161600
• ID de substância PubChem: 329766615
• NACRES: NA.22

Propriedades

• Ensaio: 95%
• forma: solid
• Características: generation 2
• adequação da reação: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: C-H Activation; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• pf: 244-246 °C
• grupo funcional: phosphine
• cadeia de caracteres SMILES: NC1=C(C2=C([Pd]Cl)C=CC=C2)C=CC=C1.C3(CCCCC3)P(C4CCCCC4)C5CCCCC5
• InChI: 1S/C18H33P.C12H10N.ClH.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h16-18H,1-15H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
• chave InChI: CYJRABDADOSMKA-UHFFFAOYSA-M

Descrição

Aplicação

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:

• To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
• To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
• In the C-H bond functionalization reactions.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable