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Key Documents

736015

Sigma-Aldrich

D149 Dye

98% (HPLC)

Sinônimo(s):

5-[[4-[4-(2,2-Diphenylethenyl)phenyl]-1,2,3-3a,4,8b-hexahydrocyclopent[b]indol-7-yl]methylene]-2-(3-ethyl-4-oxo-2-thioxo-5-thiazolidinylidene)-4-oxo-3-thiazolidineacetic acid, Indoline dye D149, Purple Dye

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About This Item

Fórmula empírica (Notação de Hill):
C42H35N3O4S3
Número CAS:
Peso molecular:
741.94
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

Ensaio

98% (HPLC)

forma

solid

pf

284-289 °C

λmax

531 nm

cadeia de caracteres SMILES

CCN1C(=S)SC(\C1=O)=C2\SC(=C/c3ccc4N(C5CCCC5c4c3)c6ccc(cc6)\C=C(\c7ccccc7)c8ccccc8)\C(=O)N2CC(O)=O

InChI

1S/C42H35N3O4S3/c1-2-43-40(49)38(52-42(43)50)41-44(25-37(46)47)39(48)36(51-41)24-27-18-21-35-33(23-27)31-14-9-15-34(31)45(35)30-19-16-26(17-20-30)22-32(28-10-5-3-6-11-28)29-12-7-4-8-13-29/h3-8,10-13,16-24,31,34H,2,9,14-15,25H2,1H3,(H,46,47)/b36-24-,41-38+

chave InChI

OZFUEQNYOBIXTB-SJIUXOFISA-N

Categorias relacionadas

Descrição geral

D149 Dye is an indoline dye that has an extinction coefficient of 68700 mol-1cm. It has a high conversion efficiency and can be used as a sensitizer.

Aplicação

D149 dye can be used as an organic dye to enhance the absorption of dye sensitized solar cells (DSSCs).
Open-circuit Voltage - Voc(mV) - 708.6
Jsc(mA/cm2) = 14.05
Fill factor − ff − 0.67
Efficiency − η − 6.67

Cell area: 0.25 cm2 (0.5 cm × 0.5 cm)
TiO2 Thickness: 5 μm
FTO glass: AGC Fabritec A11DU80
TiO2: screen printing (Catalysts & Chemicals IND. Co., Ltd.
PST−18NR/400C (4/1 mixture paste)
Electrolyte; 0.1 M LiI; 0.05 M I2; 0.6 M Dimethylpropylimidazolium
Iodide; 0.05 M t-Butylpyridine in 3-Methoxypropionitrile
Light source: AM1.5 1sun
Counter Electrode: Pt/Cr spatter glass
Dye adsorption: 30 °C/ in 3 hr. (t-BuOH/acetonitrile soln.)
Photosensitive Red-Violet dye having excellent photoelectric conversion efficiency as a metal-free dye.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Coumarin 30 Dye content 99 %

Sigma-Aldrich

546127

Coumarin 30

Characterization of solid-state dye-sensitized solar cells utilizing high absorption coefficient metal-free organic dyes
Howie WH, et al.
Journal of the American Chemical Society, 130(4), 1367-1375 (2008)
Organic dye-sensitized ionic liquid based solar cells: remarkable enhancement in performance through molecular design of indoline sensitizers
Kuang D, et al.
Advanced Materials, 120(10), 1949-1953 (2008)
High-conversion-efficiency organic dye-sensitized solar cells with a novel indoline dye
Ito S, et al.
Chemical Communications (Cambridge, England), 126(41), 5194-5196 (2008)
S. Itoh
Advanced Materials, 18, 1202-1202 (2006)
High efficiency of dye-sensitized solar cells based on metal-free indoline dyes
Horiuchi T, et al.
Journal of the American Chemical Society, 126(39), 12218-12219 (2004)

Artigos

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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