530689
Polyaniline (emeraldine base)
average Mw ~65,000
Sinônimo(s):
Emeraldine base polyaniline
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About This Item
Produtos recomendados
peso molecular
average Mw ~65,000
pf
>350 °C
solubilidade
m-cresol: soluble
DMAC: soluble
DMF: soluble
DMSO: soluble
NMP: soluble
λmax
331 nm
InChI
1S/C3H4BrN3.ClH/c1-2-3(4)6-7-5-2;/h1H3,(H,5,6,7);1H
chave InChI
LYCWKZFKTMHXQA-UHFFFAOYSA-N
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Descrição geral
Polyaniline (PAni) emeraldine salt can be prepared by protonation of PAni emeraldine base (PAni-EB). PAni-EB forms at pH>7. Its mechanism against corrosive agents has been explained in a study.
Polyaniline (emeraldine base) (PANI) is a conductive polymer which consists of a ring structure attached with nitrogen substituted derivatives. It has an emeraldine type oxidation state that exists in the form of its base. It can be prepared by deprotonation of emeraldine hydrochloric acid and ammonium hydroxide. It is mainly used in the development of electrochemical devices.
Aplicação
PANI forms a conjugating polymeric system that can be used for a variety of semiconducting applications. It can be used in the fabrication of a variety of devices which include fuel cells, light emitting diodes supercapacitors, chemical sensors and rechargeable batteries.
PAni-EB/Polyacrylonitrile (PAN) composite nanofibers were fabricated. The effect of the concentration of dopant and solvent on the morphology, conductivity and mechanical properties of the composites were studied. Preparation of PAni-EB/PAN nanoweb has also been reported.
Características e benefícios
Undoped form of conducting polymer (non-conductive).
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
Eyeshields, Gloves, type N95 (US)
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Application of polyaniline (emeraldine base, EB) in polymer light-emitting devices.
Synthetic Metals, 78(1), 33-37 (1996)
Supercapacitors based on flexible graphene/polyaniline nanofiber composite films
ACS Nano, 4(4), 1963-1970 (2010)
A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries
Advanced Energy Materials, 2(10), 1238-1245 (2012)
Conducting-polymer-based supercapacitor devices and electrodes
Journal of Power Sources, 196(1), 1-12 (2011)
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