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530689

Sigma-Aldrich

Polyaniline (emeraldine base)

average Mw ~65,000

Sinônimo(s):

Emeraldine base polyaniline

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About This Item

Número CAS:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

peso molecular

average Mw ~65,000

pf

>350 °C

solubilidade

m-cresol: soluble
DMAC: soluble
DMF: soluble
DMSO: soluble
NMP: soluble

λmax

331 nm

InChI

1S/C3H4BrN3.ClH/c1-2-3(4)6-7-5-2;/h1H3,(H,5,6,7);1H

chave InChI

LYCWKZFKTMHXQA-UHFFFAOYSA-N

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Descrição geral

Polyaniline (PAni) emeraldine salt can be prepared by protonation of PAni emeraldine base (PAni-EB). PAni-EB forms at pH>7. Its mechanism against corrosive agents has been explained in a study.
Polyaniline (emeraldine base) (PANI) is a conductive polymer which consists of a ring structure attached with nitrogen substituted derivatives. It has an emeraldine type oxidation state that exists in the form of its base. It can be prepared by deprotonation of emeraldine hydrochloric acid and ammonium hydroxide. It is mainly used in the development of electrochemical devices.

Aplicação

PANI forms a conjugating polymeric system that can be used for a variety of semiconducting applications. It can be used in the fabrication of a variety of devices which include fuel cells, light emitting diodes supercapacitors, chemical sensors and rechargeable batteries.
PAni-EB/Polyacrylonitrile (PAN) composite nanofibers were fabricated. The effect of the concentration of dopant and solvent on the morphology, conductivity and mechanical properties of the composites were studied. Preparation of PAni-EB/PAN nanoweb has also been reported.

Características e benefícios

Undoped form of conducting polymer (non-conductive).

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


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Carbon nanotube/polyaniline composite as anode material for microbial fuel cells
Qiao Y, et al.
Journal of Power Sources, 170(1), 79-84 (2007)
Application of polyaniline (emeraldine base, EB) in polymer light-emitting devices.
Wang HL, et al.
Synthetic Metals, 78(1), 33-37 (1996)
Supercapacitors based on flexible graphene/polyaniline nanofiber composite films
Wu Q, et al.
ACS Nano, 4(4), 1963-1970 (2010)
A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries
Li G, et al.
Advanced Energy Materials, 2(10), 1238-1245 (2012)
Conducting-polymer-based supercapacitor devices and electrodes
Snook GA, et al.
Journal of Power Sources, 196(1), 1-12 (2011)

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