409405

Chlorotris(trimethylsilyl)silane

97%

• Sinônimo(s): 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
• Fórmula linear: [(CH₃)₃Si]₃SiCl
• Número CAS: 5565-32-2
• Peso molecular: 283.11
• Número MDL: MFCD01321222
• Código UNSPSC: 12352101
• ID de substância PubChem: 24865643
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: 97%
• forma: solid
• pf: 50-52 °C (lit.)
• cadeia de caracteres SMILES: C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
• chave InChI: HCOROOJWVHFMRJ-UHFFFAOYSA-N

Descrição

Descrição geral

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

Aplicação

Super Silyl Protecting Groups

Used for:

• Insertion into a P-P bond
• Diastereoselective aldol and cascade reactions
• Preparation of hypersilyl substituted monophosphines and diphosphines

Informações de segurança

• Pictogramas: GHS02,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H228,H261,H315,H319,H335
• Declarações de precaução: P210 - P231 + P232 - P240 - P241 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3
• Órgãos-alvo: Respiratory system
• Perigos de suplementos: EUH029
• Código de classe de armazenamento: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 87.8 °F - closed cup
• Ponto de fulgor (°C): 31 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges