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270784

Sigma-Aldrich

4-(Chloromethyl)benzoyl chloride

97%

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About This Item

Fórmula linear:
ClCH2C6H4COCl
Número CAS:
876-08-4
Peso molecular:
189.04
Número CE:
212-881-0
Número MDL:
MFCD00053224
Código UNSPSC:
12352100
ID de substância PubChem:
24856399
NACRES:
NA.22

Nível de qualidade

200

Ensaio

97%

pb

126-128 °C/6 mmHg (lit.)

pf

30-32 °C (lit.)

cadeia de caracteres SMILES

ClCc1ccc(cc1)C(Cl)=O

InChI

1S/C8H6Cl2O/c9-5-6-1-3-7(4-2-6)8(10)11/h1-4H,5H2

chave InChI

RCOVTJVRTZGSBP-UHFFFAOYSA-N

Categorias relacionadas

Aplicação

4-(Chloromethyl)benzoyl chloride was used as an atom transfer radical polymerization (ATRP) initiator in the growth of polyacrylamide (PAAm) brushes from silicon wafers. It was also used as a building block in a microwave-assisted, solid-phase synthesis of imatinib, an anticancer agent.

Pictogramas

CorrosionExclamation mark
GHS05,GHS07

Palavra indicadora

Danger

Frases de perigo

H314,H335

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

199.4 °F - closed cup

Ponto de fulgor (°C)

93 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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Irina Cringus-Fundeanu et al.
Langmuir : the ACS journal of surfaces and colloids, 23(9), 5120-5126 (2007-03-29)
A method is presented to prevent microbial adhesion to solid surfaces exploiting the unique properties of polymer brushes. Polyacrylamide (PAAm) brushes were grown from silicon wafers by atom transfer radical polymerization (ATRP) using a three-step reaction procedure consisting of immobilization
Tetrahedron Letters, 48, 3455-3455 (2007)
Song Yi Lee et al.
ACS applied materials & interfaces, 10(43), 36628-36640 (2018-10-10)
CD44 receptor targeting and lipid rafts destroying nanoassembly (NA) was developed for breast cancer therapy. Methyl-β-cyclodextrin (MbCD), as a cholesterol depletion moiety, was conjugated to hyaluronic acid-ceramide (HACE) structure via an ester linkage. HACE-MbCD NA with 198 nm hydrodynamic size
Ali Bilgic et al.
Journal of fluorescence, 30(4), 867-881 (2020-06-05)
In this study, we developed two different very sensitive magnetite fluorescent Fe3O4@SiO2-TPED-BODIPY and Fe3O4@SiO2-TMPTA-BODIPY nano-sensors for the selective detection of Cr(VI) ions. The Cr(VI) metal ions sensing is based on the fluorescent quenching of BODIPY functionalized with Fe3O4@SiO2-TPED and Fe3O4@SiO2-TMPTA
Andrej Babič et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(6), 1348-1357 (2017-11-10)
Gadolinium-loaded nanomicelles show promise as future magnetic resonance imaging (MRI) contrast agents (CAs). Their increased size and high gadolinium (Gd) loading gives them an edge in proton relaxivity over smaller molecular Gd-complexes. Their size and stealth properties are fundamental for
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