923443

PhMPhos

• Synonyme(s) : 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• Formule empirique (notation de Hill): C₄₂H₄₈FeP₂
• Poids moléculaire : 670.62
• Code UNSPSC : 12352200
• Nomenclature NACRES : NA.21

Propriétés

• Forme: powder
• Niveau de qualité: 100
• Pertinence de la réaction: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• Groupe fonctionnel: phosphine

Description

Application

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Autres remarques

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable