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310700
Mangan(IV)-oxid
10 μm, reagent grade, ≥90%
Synonym(e):
Mangandioxid
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About This Item
Empfohlene Produkte
Qualität
reagent grade
Qualitätsniveau
Assay
≥90%
Form
powder
Partikelgröße
10 μm
mp (Schmelzpunkt)
535 °C (dec.) (lit.)
SMILES String
O=[Mn]=O
InChI
1S/Mn.2O
InChIKey
NUJOXMJBOLGQSY-UHFFFAOYSA-N
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Allgemeine Beschreibung
Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions.
Anwendung
- High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018).
- Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation
Zielorgane
Brain
Lagerklassenschlüssel
13 - Non Combustible Solids
WGK
WGK 2
Flammpunkt (°F)
does not flash
Flammpunkt (°C)
does not flash
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