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Merck

43861

Supelco

Furan

analytical standard

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About This Item

Empirische Formel (Hill-System):
C4H4O
CAS-Nummer:
Molekulargewicht:
68.07
Beilstein:
103221
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
85151701
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Dampfdichte

2.35 (vs air)

Dampfdruck

1672 mmHg ( 55 °C)
31.66 psi ( 55 °C)
493 mmHg ( 20 °C)
9.22 psi ( 20 °C)

Assay

≥98.0% (GC)

Haltbarkeit

limited shelf life, expiry date on the label

Enthält

~0.025% 2,6-di-tert-4-methylphenol as stabilizer

Expl.-Gr.

14.3 %

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Brechungsindex

n20/D 1.421 (lit.)
n20/D 1.421

bp

32 °C/758 mmHg (lit.)

Dichte

0.936 g/mL at 25 °C (lit.)

Anwendung(en)

cleaning products
cosmetics
environmental
food and beverages
personal care

Format

neat

Lagertemp.

2-8°C

SMILES String

c1ccoc1

InChI

1S/C4H4O/c1-2-4-5-3-1/h1-4H

InChIKey

YLQBMQCUIZJEEH-UHFFFAOYSA-N

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Allgemeine Beschreibung

Furan is a clear and colorless liquid, and a bimolecular heterocycle, which can be used to trap unstable intermediates containing highly reactive species, via Diels-Alder cycloaddition reactions.
Furan, a naturally occurring compound associated with the flavor of food, is found at very low levels in a variety of food products and beverages. It finds applications as a solvent for resins and lacquers as well as in the preparation of organic compounds, in pharmaceuticals, etc. Furan is also reportedly identified in heat treated food products, including cooked chicken, fish protein concentrate, caramel back, canned meat, bread, coffee, etc.

Anwendung

Furan can undergo Diels-Alder [4+2] cycloaddition reaction with maleic anhydride to form the corresponding exo and endo furan-maleic anhydride adducts.
Furan may be used as an analytical reference standard for the quantification of the analyte in heat-processed foods using gas chromatography-mass spectrometry (GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2 - Skin Irrit. 2 - STOT RE 2

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

-32.8 °F - closed cup

Flammpunkt (°C)

-36 °C - closed cup


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Analysenzertifikate (COA)

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Slide 1 of 3

1 of 3

Synthetic applications of furan Diels-Alder chemistry
Kappe O.C, et al.
Tetrahedron, 53(42), 14179-14233 (1997)
Analysis of furan in heat-processed foods in China by automated headspace gas chromatography-mass spectrometry (HS-GC-MS)
Nie P-S, et al.
Food Control, 30(1), 62-68 (2013)
Carolin Neuwirth et al.
Molecular nutrition & food research, 56(9), 1363-1374 (2012-08-07)
Furan is a potent hepatotoxicant and liver carcinogen in rodents. However, short-term tests for genotoxicity of furan are inconclusive. The aim of this study was to assess the potential of furan to covalently bind to DNA, and to assess furan
C W Heppner et al.
Food additives and contaminants, 24 Suppl 1, 114-121 (2007-09-22)
Furan is an organic, volatile compound used in various chemical-manufacturing industries. Headspace gas chromatography is the analytical method of choice for obtaining reliable results on its occurrence. The presence of furan in some food items has been known since the
Rialet Pieters et al.
Environment international, 66, 71-78 (2014-02-18)
In South Africa, 26-50% of households use solid fuel for cooking food and heating houses. When used as fuel, wood and chlorinated waste are known sources of polychlorinated dibenzo-para-dioxins, polychlorinated dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs). Here, we compare PCDD/F

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