ALD00386

Fe(dibm)₃

• Synonym(e): Baran Olefin Cross-Coupling Catalyst, Iron tris(diisobutyrylmethane)
• Empirische Formel (Hill-System): C₂₇H₄₅FeO₆
• CAS-Nummer: 24444-72-2
• Molekulargewicht: 521.49
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329772664
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Eignung der Reaktion: core: iron; reagent type: catalyst
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): 96-102 °C
• Grünere Alternativprodukt-Kategorie: Aligned,
• SMILES String: O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.O=C([CH-]C(C(C)C)=O)C(C)C.[Fe+3]
• InChI: 1S/3C9H15O2.Fe/c3*1-6(2)8(10)5-9(11)7(3)4;/h3*5-7H,1-4H3;/q3*-1;+3
• InChIKey: LKNJSJQVZKKQHU-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions.

Sonstige Hinweise

The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling

Functionalized olefin cross-coupling to construct carbon–carbon bonds

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable