700223

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)mangan(III)

97%

• Synonym(e): (Mn(TMHD)₃)
• Lineare Formel: Mn(C₁₁H₁₉O₂)₃
• CAS-Nummer: 14324-99-3
• Molekulargewicht: 604.74
• MDL-Nummer: MFCD00269825
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329762189
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: crystals
• Eignung der Reaktion: core: manganese; reagent type: catalyst
• mp (Schmelzpunkt): 160-170 °C
• SMILES String: CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
• InChIKey: ORZPLLPBZHORSD-LWTKGLMZSA-K

Beschreibung

Anwendung

Catalyst for:

• Intramolecular Diels-Alder reactions
• Single electron donor for excess electron transfer studies in DNA
• Enantioselective synthesis
• Borylation reactions
• Hydrohydrazination and hydroazidation
• Oxidative carbonylation of phenol

Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves