809330

Fe/ppm Pd for nitro group reductions

• MDL-Nummer: MFCD00011005
• UNSPSC-Code: 12161600
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Zusammensetzung: FeCl₂ (372870), 23.3-27.4 wt. % ; MgCl₂ (M8266), 15.3-18.8 wt. % ; Pd (203939), <0.3 wt. % ; THF (186562), 53.5-61.6 wt. %
• Eignung der Reaktion: core: iron; reagent type: catalyst
• Lagertemp.: 2-8°C
• SMILES String: [Fe](Cl)(Cl)Cl

Beschreibung

Anwendung

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Vorsicht

Handle under nitrogen and store under argon in refrigerator.

Sonstige Hinweise

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature

Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H290,H302,H318,H335,H351
• P-Sätze: P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH018,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 2
• Flammpunkt (°F): 1.4 °F
• Flammpunkt (°C): -17 °C