692182

(R)-Ru(OAc)₂(DM-SEGPHOS^®)

• Synonym(e): Diacetato-[(R)-5,5′-bis-[di-(3,5-xylyl)-phosphino]-4,4′-bi-1,3-benzodioxol]-ruthenium(II)
• Empirische Formel (Hill-System): C₅₀H₅₀O₈P₂Ru
• Molekulargewicht: 941.94
• MDL-Nummer: MFCD09753025
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761472
• NACRES: NA.22

Eigenschaften

• Form: powder
• Lagertemp.: 2-8°C
• SMILES String: CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8
• InChI: 1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2
• InChIKey: ACKYBTAGKAINOG-UHFFFAOYSA-L

Beschreibung

Anwendung

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:

• Stereoselective preparation of β-amino amides via ruthenium segphos complex-catalyzed asymmetric reductive amination of β-keto amides

Rechtliche Hinweise

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable