65671

(R)-1-{(R_P)-2-[2-(Diphenylphosphino)-phenyl]-ferrocenyl}-ethylbis-[3,5-bis-(trifluormethyl)-phenyl]-phosphin

≥97%

• Synonym(e): (1S)-1-[(1R)-1-[Bis-[3,5-bis-(trifluormethyl)-phenyl]-phosphino]-ethyl]-2-[2-(diphenylphosphino)-phenyl]-ferrocen (nach CAS), Walphos SL-W001-1
• Empirische Formel (Hill-System): C₄₆H₃₂F₁₂FeP₂
• CAS-Nummer: 387868-06-6
• Molekulargewicht: 930.52
• MDL-Nummer: MFCD08561122
• UNSPSC-Code: 12352101
• PubChem Substanz-ID: 24884219
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥97%
• Optische Reinheit: ee: ≥99%
• SMILES String: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
• InChI: 1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1
• InChIKey: LKNKYBWIZNAXBY-WLOLSGMKSA-N

Beschreibung

Allgemeine Beschreibung

The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.

Anwendung

Walphos SL-W001-2, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:

• Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
• Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Sonstige Hinweise

Verkauf in Zusammenarbeit mit Solvias AG

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)