567159

1,1′-Bis(phenylphosphiniden)ferrocen

97%

• Synonym(e): 1,1′-(Ferrocendiyl)phenylphosphin
• Lineare Formel: C₅H₄PC₆H₅C₅H₄Fe
• CAS-Nummer: 72954-06-4
• Molekulargewicht: 292.09
• MDL-Nummer: MFCD04974069
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24880349
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp (Schmelzpunkt): 88-92 °C (lit.)
• Funktionelle Gruppe: phosphine
• Lagertemp.: 2-8°C
• SMILES String: [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
• InChI: 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
• InChIKey: HKOUDNXXOXEYNZ-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)