563110

Azodicarbonsäure-diethylester -Lösung

40 wt. % in toluene

• Synonym(e): DEAD
• Lineare Formel: C₂H₅OCON=NCOOC₂H₅
• CAS-Nummer: 1972-28-7
• Molekulargewicht: 174.15
• Beilstein: 908662
• MDL-Nummer: MFCD00009103
• UNSPSC-Code: 12352108
• PubChem Substanz-ID: 24880080

Eigenschaften

• Qualitätsniveau: 100
• Konzentration: 40 wt. % in toluene
• Brechungsindex: n20/D 1.4690
• bp: 116-117 °C
• Dichte: 0.956 g/mL at 25 °C
• Funktionelle Gruppe: azo
• Lagertemp.: 2-8°C
• SMILES String: CCOC(=O)\N=N/C(=O)OCC
• InChI: 1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+
• InChIKey: FAMRKDQNMBBFBR-BQYQJAHWSA-N

Beschreibung

Allgemeine Beschreibung

DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.

Anwendung

A commonly used activating reagent in Mitsunobo reactions.

Reactant for preparation of:

• Immunostimulants α-Galactosylceramides
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes

Reagent for:

• Annulation of N-protected imines
• α-thiocyanation of enolizable ketones with ammonium thiocyanate
• Diels-Alder reactions

Verpackung

100g unit contains ca. 40g DEAD solute

25g unit contains ca. 10g DEAD solute

Warnhinweis

Toxic, Irritant, Flammable

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H226,H242,H304,H315,H319,H335,H336,H361d,H373,H412
• P-Sätze: P210 - P301 + P310 - P331 - P370 + P378 - P403 + P233 - P403 + P235
• Gefahreneinstufungen: Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Self-react. C - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system
• Lagerklassenschlüssel: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 105.8 °F - closed cup
• Flammpunkt (°C): 41 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter