530689
Polyanilin (Emeraldinbase)
average Mw ~65,000
Synonym(e):
Polyanilin-Emeraldinbase
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About This Item
Empfohlene Produkte
Mol-Gew.
average Mw ~65,000
mp (Schmelzpunkt)
>350 °C
Löslichkeit
m-cresol: soluble
DMAC: soluble
DMF: soluble
DMSO: soluble
NMP: soluble
λmax
331 nm
InChI
1S/C3H4BrN3.ClH/c1-2-3(4)6-7-5-2;/h1H3,(H,5,6,7);1H
InChIKey
LYCWKZFKTMHXQA-UHFFFAOYSA-N
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Allgemeine Beschreibung
Polyaniline (PAni) emeraldine salt can be prepared by protonation of PAni emeraldine base (PAni-EB). PAni-EB forms at pH>7. Its mechanism against corrosive agents has been explained in a study.
Polyaniline (emeraldine base) (PANI) is a conductive polymer which consists of a ring structure attached with nitrogen substituted derivatives. It has an emeraldine type oxidation state that exists in the form of its base. It can be prepared by deprotonation of emeraldine hydrochloric acid and ammonium hydroxide. It is mainly used in the development of electrochemical devices.
Anwendung
PANI forms a conjugating polymeric system that can be used for a variety of semiconducting applications. It can be used in the fabrication of a variety of devices which include fuel cells, light emitting diodes supercapacitors, chemical sensors and rechargeable batteries.
PAni-EB/Polyacrylonitrile (PAN) composite nanofibers were fabricated. The effect of the concentration of dopant and solvent on the morphology, conductivity and mechanical properties of the composites were studied. Preparation of PAni-EB/PAN nanoweb has also been reported.
Leistungsmerkmale und Vorteile
Undoped form of conducting polymer (non-conductive).
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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Carbon nanotube/polyaniline composite as anode material for microbial fuel cells
Journal of Power Sources, 170(1), 79-84 (2007)
Application of polyaniline (emeraldine base, EB) in polymer light-emitting devices.
Synthetic Metals, 78(1), 33-37 (1996)
Supercapacitors based on flexible graphene/polyaniline nanofiber composite films
ACS Nano, 4(4), 1963-1970 (2010)
A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries
Advanced Energy Materials, 2(10), 1238-1245 (2012)
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