429147

(Acetylacetonat)dicarbonyliridium(I)

• Synonym(e): Dicarbonyl(2,4-pentanedionato)iridium
• Lineare Formel: Ir(acac)(CO₂)
• CAS-Nummer: 14023-80-4
• Molekulargewicht: 347.35
• MDL-Nummer: MFCD00049135
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24866841
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: core: iridium; reagent type: catalyst
• SMILES String: [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]
• InChI: 1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
• InChIKey: DFIAYCFHPDOZLK-FGSKAQBVSA-M

Beschreibung

Anwendung

Catalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:

• Oxidative addition of perfluoroalkyl iodides
• Synthesis of iridium heterocycles
• Scaffolding of iridium complexes
• Metal carbonyl cluster synthesis
• Mixed-bridged bimetallic d8 complex synthesis

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Warning
• H-Sätze: H302 + H312 + H332,H315,H319,H335,H361
• P-Sätze: P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves