422886

(S)-(+)-2-(Aminomethyl)pyrrolidin

97%

• Empirische Formel (Hill-System): C₅H₁₂N₂
• CAS-Nummer: 69500-64-7
• Molekulargewicht: 100.16
• MDL-Nummer: MFCD00191745
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24866461
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: liquid
• Optische Aktivität: [α]20/D +20°, c = 1 in chloroform
• Brechungsindex: n20/D 1.482 (lit.)
• bp: 65 °C/11 mmHg (lit.)
• Dichte: 0.933 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine
• SMILES String: NC[C@@H]1CCCN1
• InChI: 1S/C5H12N2/c6-4-5-2-1-3-7-5/h5,7H,1-4,6H2/t5-/m0/s1
• InChIKey: AUKXFNABVHIUAC-YFKPBYRVSA-N

Beschreibung

Allgemeine Beschreibung

(S)-(+)-2-(Aminomethyl)pyrrolidine is a chiral vicinal diamine.

Anwendung

Used in the synthesis of compounds with antitumor activity.

(S)-(+)-2-(Aminomethyl)pyrrolidine can be used as an organocatalyst:

• For the asymmetric transformation of (S)-alanine.
• In the asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.

It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 116.6 °F - closed cup
• Flammpunkt (°C): 47 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter