417602

2-Chlorethylphenylsulfid

98%

• Synonym(e): 2-(Phenylthio)-ethylchlorid
• Lineare Formel: ClCH₂CH₂SC₆H₅
• CAS-Nummer: 5535-49-9
• Molekulargewicht: 172.68
• Beilstein: 1907116
• EG-Nummer: 226-891-8
• MDL-Nummer: MFCD00013691
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24866164
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.583 (lit.)
• bp: 90-91 °C/1 mmHg (lit.)
• Dichte: 1.174 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: chloro; thioether
• SMILES String: ClCCSc1ccccc1
• InChI: 1S/C8H9ClS/c9-6-7-10-8-4-2-1-3-5-8/h1-5H,6-7H2
• InChIKey: QDXIHHOPZFCEAP-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2-Chloroethyl phenyl sulfide has been reported as sulfur mustard simulant. It is a chemical-warfare agent (CWA) simulant and its oxidation using hydrothane films has been reported. It is also reported as a simulant for the chemical warfare agent mustard [bis(2-chloroethyl) sulfide]. Its reaction with vesicular functionalized double-chain surfactant (potassium O, O′-didodecylphosphorodithioate) at pH 9.0 borate buffer affords [S-[(2-phenylthio)ethyl]O,O′-didodecylphosphorodithioate]. Its oxidation with H₂O₂ catalyzed by [MnL](ClO₄)₂ (L = N,N′,N″-tris(2-hydroxypropyl)-1,4,7-triazacyclononane) afforded 2-chloroethyl phenyl sulfone and phenyl vinyl sulfone.

Anwendung

2-Chloroethyl phenyl sulfide, a sulfur mustard agent stimulant, may be used as target analyte in a bioassay for the detection of mustard agent.

Sicherheitshinweise

• Piktogramme: GHS06,GHS08,GHS05
• Signalwort: Danger
• H-Sätze: H311 + H331,H314,H350
• P-Sätze: P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Carc. 1A - Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 219.2 °F - closed cup
• Flammpunkt (°C): 104 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter