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Ethylformimidat -hydrochlorid
Synonym(e):
Ethyl methanimidate hydrochloride
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About This Item
Empfohlene Produkte
Form
solid
Qualitätsniveau
mp (Schmelzpunkt)
75 °C (dec.) (lit.)
Funktionelle Gruppe
ether
Lagertemp.
2-8°C
SMILES String
Cl.CCOC=N
InChI
1S/C3H7NO.ClH/c1-2-5-3-4;/h3-4H,2H2,1H3;1H
InChIKey
JPUTTYRVDANTBN-UHFFFAOYSA-N
Allgemeine Beschreibung
Ethyl formimidate hydrochloride is a nitrogen containing organic building block. On heating it undergoes degradation to afford formamidine hydrochloride, ethyl formate and ethyl chloride.
Anwendung
Ethyl formimidate hydrochloride may be used in the preparation of the following:
- 5-aminoimidazole-4-carboxylic acid α- and β-ribotides
- s-triazines
- 2,3:5,6-di-O-isopropylidene-α- and -β-5-amino-4-ethoxycarbonyl or -carbamoyl-imidazole D-mannofuranosides
- 5-amino-1-(2-pyridyl)imidazole
Reactant involved in the synthesis of biologically active molecules including:
Reactant involved in:
- Bredinin via amination of an acyclic precursor
- Amidine conjugates of the ornithine moiety of an antifungal
Reactant involved in:
- Intermolecular cyclization
- Mo-catalyzed asymmetric ring-closing metathesis for synthesis of cyclid amides and amines
- Synthesis of peptidic 1-cyanopyrrolidines
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Purines, pyrimidines, and imidazoles part 54. Interconversion of some intermediates in the de novo biosynthesis of purine nucleotides.
Journal of the Chemical Society. Perkin Transactions 1, 2316-2321 (1980)
Purines, pyrimidines, and imidazoles. Part XLI. Glycofuranosylamines derived from D-xylose, D-glucose, D-mannose, and L-rhamnose and their use in the synthesis of pyrimidine and imidazole nucleosides.
Journal of the Chemical Society. Perkin Transactions 1, 73-81 (1974)
Purines, pyrimidines, and imidazoles. XL. A new synthesis of a D-ribofuranosylamine derivative and its use in the synthesis of pyrimidine and imidazole nucleosides.
Journal of the Chemical Society. Perkin transactions 1, 16, 1720-1731 (1973-01-01)
Synthesis of the S-Triazine System. Iii. 1 Trimerization of Imidates.
The Journal of Organic Chemistry, 26(8), 2771-2784 (1961)
Chemistry of Organic Compounds: Pt. B. Aliphatic compounds, 551-551 (1951)
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