327956

(1R)-(+)-Nopinon

98%

• Synonym(e): 6,6-Dimethylbicyclo[3.1.1]heptan-2-on
• Empirische Formel (Hill-System): C₉H₁₄O
• CAS-Nummer: 38651-65-9
• Molekulargewicht: 138.21
• MDL-Nummer: MFCD08447116
• UNSPSC-Code: 12352115
• PubChem Substanz-ID: 24859704
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Form: liquid
• Optische Aktivität: [α]20/D +16°, neat
• Brechungsindex: n20/D 1.479 (lit.)
• bp: 209 °C (lit.)
• Dichte: 0.981 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ketone
• Lagertemp.: 2-8°C
• SMILES String: CC1(C)[C@H]2CCC(=O)[C@@H]1C2
• InChI: 1S/C9H14O/c1-9(2)6-3-4-8(10)7(9)5-6/h6-7H,3-5H2,1-2H3/t6-,7-/m0/s1
• InChIKey: XZFDKWMYCUEKSS-BQBZGAKWSA-N

Beschreibung

Anwendung

(1R)-(+)-Nopinone may be used in the preparation of a chiral annulated indene derivative, which can be a potentially useful chiral ligand for transition metal complexes in asymmetric transformations. It may also react with secondary amines in cyclohexane to form the corresponding enamines.

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 167.0 °F - closed cup
• Flammpunkt (°C): 75 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)