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Merck

209988

Sigma-Aldrich

Zink

dust, <10 μm, ≥98%

Synonym(e):

Zn

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About This Item

Empirische Formel (Hill-System):
Zn
CAS-Nummer:
Molekulargewicht:
65.39
MDL-Nummer:
UNSPSC-Code:
12161600
PubChem Substanz-ID:
NACRES:
NA.22

Dampfdruck

1 mmHg ( 487 °C)

Qualitätsniveau

Assay

≥98%

Form

dust

Eignung der Reaktion

core: zinc
reagent type: catalyst

Widerstandsfähigkeit

5.8 μΩ-cm, 20°C

Partikelgröße

<10 μm

bp

907 °C (lit.)

mp (Schmelzpunkt)

420 °C (lit.)

Dichte

7.133 g/mL at 25 °C (lit.)

SMILES String

[Zn]

InChI

1S/Zn

InChIKey

HCHKCACWOHOZIP-UHFFFAOYSA-N

Allgemeine Beschreibung

Zinc is an inexpensive, readily available versatile reagent in organic reactions and is commonly used as a reducing agent in organic synthesis. Zinc dust is used to reduce carbonyls, carbon-halide bonds, carbon-oxygen bonds, alkynes, and heteroatom bonds such as N-N and N-O bonds. It is also used to prepare various organozinc reagents. Additionally, Zinc has been used in several well-known named reactions, like the Reformatsky reaction, the Knorr pyrrole synthesis, the Serini reaction, and the Simmons-Smith cyclopropanation.

Anwendung

Reducing agent; used for preparation of organozinc reagents, Reformatsky reagents, and the Simmons-Smith reagent (cyclopropanation).

Zinc is also used as a:

  • Reductant in the hydrothermal CO2 reduction to formic acid in batch reactors.
  • Catalyst in the synthesis of propargylamines by one pot, three component coupling of aldehydes, amines and alkynes in acetonitrile.

Piktogramme

Environment

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves


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Green chemistry : an international journal and green chemistry resource : GC, 2015, 307-307 (2014-12-23)
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Knochel, P.
Chemical Reviews, 93, 217-217 (1993)
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