124087

2-Brom-4-methylanilin

98%

• Synonym(e): 2-Brom-p-toluidin, 4-Amino-3-brom-toluol
• Lineare Formel: BrC₆H₃(CH₃)NH₂
• CAS-Nummer: 583-68-6
• Molekulargewicht: 186.05
• Beilstein: 1931711
• EG-Nummer: 209-515-7
• MDL-Nummer: MFCD00007635
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24847595
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.602 (lit.)
• bp: 240 °C (lit.)
• mp (Schmelzpunkt): 14-16 °C (lit.)
• Dichte: 1.5 g/mL at 25 °C (lit.)
• SMILES String: Cc1ccc(N)c(Br)c1
• InChI: 1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
• InChIKey: UVRRJILIXQAAFK-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me₃Al to form amide.

Anwendung

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.

Sicherheitshinweise

• Piktogramme: GHS06
• Signalwort: Danger
• H-Sätze: H301 + H311 + H331
• P-Sätze: P261 - P264 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): 230.0 °F - closed cup
• Flammpunkt (°C): 110 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter