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P29006

Sigma-Aldrich

Phenylphosphonic acid

98%

Sinónimos:

Benzene phosphonic acid

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About This Item

Fórmula lineal:
C6H5P(O)(OH)2
Número de CAS:
1571-33-1
Peso molecular:
158.09
Beilstein/REAXYS Number:
2245168
EC Number:
216-388-1
MDL number:
MFCD00002136
UNSPSC Code:
12352300
PubChem Substance ID:
24898371
NACRES:
NA.23

Quality Level

200

assay

98%

form

crystals

mp

162-164 °C (lit.)

SMILES string

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChI key

QLZHNIAADXEJJP-UHFFFAOYSA-N

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Application

Additive used with Noyori's catalyst for oxidation of sulfides to sulfones.

Noyori Oxidation (Sodium Tungstate Dihydrate, Hydrogen Peroxide, Methyltri-n-octylammonium Hydrogen Sulfate, Phosphonic Acid)
Self assembled monolayers (SAMs)of phenylphosphonic acid may be used to make the interface between organic semiconductors and transparent conductive oxides. The acid may be used to functionalize titania particles. Additive used with Noyorι¢s catalyst for greener oxidation of sulfides to sulfones.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCM8316
MKCM0595
MKCJ5393
MKBD2147V
MKBT8259V

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Pengju Pan et al.
ACS applied materials & interfaces, 1(2), 402-411 (2009-02-25)
Layered metal phosphonate, zinc phenylphosphonate (PPZn), reinforced poly(L-lactide) (PLLA) composites were fabricated by a melt-mixing technique. The nonisothermal and isothermal crystallization, melting behavior, spherulite morphology, crystalline structure, and static and dynamic mechanical properties of the PLLA/PPZn composites were investigated. PPZn
M W Fryer et al.
Journal of muscle research and cell motility, 18(2), 161-167 (1997-04-01)
The rate, magnitude and pharmacology of inorganic phosphate (Pi) transport into the sarcoplasmic reticulum were estimated in single, mechanically skinned skeletal muscle fibres of the rat. This was done, indirectly, by using a technique that measured the total Ca2+ content
Orientation of Phenylphosphonic Acid Self-Assembled Monolayers on a Transparent Conductive Oxide: A Combined NEXAFS, PM-IRRAS, and DFT Study
Gliboff M, et al.
Langmuir, 29(7), 2166?2174-2166?2174 (2013)
Vladimir V Malygin et al.
Journal of toxicology and environmental health. Part A, 66(7), 611-625 (2003-05-15)
Inhibition of acetylcholinesterase (AChE) versus inhibition and aging of neuropathy target esterase (NTE) by organophosphorus (OP) compounds in vivo can give rise to distinct neurological consequences: acute cholinergic toxicity versus OP compound-induced delayed neurotoxicity (OPIDN). Previous work has shown that
Christel Gervais et al.
Magnetic resonance in chemistry : MRC, 42(5), 445-452 (2004-04-20)
1H, 13C, 17O and 31P NMR parameters, including chemical shift tensors and quadrupolar parameters for 17O, were calculated for phenylphosphonic acid, C6H5PO(OH)2, under periodic boundary conditions. The results are in very good agreement with experimental data and permit the unambiguous
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