593230

Phenyllithium solution

1.9 M in dibutyl ether

• Sinónimos: PhLi
• Fórmula empírica (notación de Hill): C₆H₅Li
• Número de CAS: 591-51-5
• Peso molecular: 84.04
• Beilstein/REAXYS Number: 506502
• MDL number: MFCD00014254
• UNSPSC Code: 12352103
• PubChem Substance ID: 24881428
• NACRES: NA.22

Propiedades

• Quality Level: 100
• concentration: 1.9 M in dibutyl ether
• density: 0.835 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: [Li]c1ccccc1
• InChI: 1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;
• InChI key: NHKJPPKXDNZFBJ-UHFFFAOYSA-N

Descripción

Application

Phenyllithium solution can be used to synthesize:

• 1-Acetyl-1′-diphenylphosphinoferrocene from ferrocenophane.
• Ethyl 2-acetylimino-1-benzyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from ethyl 1-benzyl-6-bromo-2-imino-1,2-dihydroquinoline-3-carboxylate.
• Ethyl 2-amino-1-benzoyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from (E)-ethyl 2-(acetylimino)-1-benzoyl-6-bromo-1,2-dihydroquinoline-3-carboxylate.

Información de seguridad

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H226,H314,H335,H412
• pcodes: P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH014
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 77.0 °F - closed cup
• flash_point_c: 25 °C - closed cup