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Merck

20159

Sigma-Aldrich

n-Butil-litio solution

2.7 M in heptane

Sinónimos:

n-BuLi, Butil litio, Butil-litio solution, Litio-1-butanida

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About This Item

Fórmula lineal:
CH3(CH2)3Li
Número de CAS:
Peso molecular:
64.06
Beilstein/REAXYS Number:
1209227
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

shelf life

limited shelf life

concentration

2.7 M in heptane

color

yellow

density

0.71 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

[Li]CCCC

InChI

1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;

InChI key

MZRVEZGGRBJDDB-UHFFFAOYSA-N

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Application

n-Butyllithium is a strong nucleophile in the synthetic organic chemistry. It is also used as an initiator in the polymerization process.

Caution

a precipitate of lithium hydride can form on longer storage

related product

Referencia del producto
Descripción
Precios

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Methylsulfinyl carbanion (CH3-SO-CH2-). Formation and applications to organic synthesis
Corey EJ and Chaykovsky M
Journal of the American Chemical Society, 87(6), 1345-1353 (1965)
Some trends observed in [60] fullerene polymerization activated by butyllithium isomers
Atovmyan EG, et al.
Russian Chemical Bulletin, 61(11), 2178-2179 (2012)
Yuqiang Ma et al.
ACS nano, 9(7), 7383-7391 (2015-07-01)
Two-dimensional (2D) semiconducting monolayer transition metal dichalcogenides (TMDCs) have stimulated lots of interest because they are direct bandgap materials that have reasonably good mobility values. However, contact between most metals and semiconducting TMDCs like 2H phase WSe2 are highly resistive
Michael A Tarselli et al.
Organic letters, 11(20), 4596-4599 (2009-10-09)
A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.
J P Parente et al.
Carbohydrate research, 141(1), 41-47 (1985-08-15)
Treatment of dimethyl sulfoxide with butyllithium leads to rapid formation of lithium methylsulfinyl carbanion. The reaction products tend to be significantly freer from impurities when lithium methylsulfinyl carbanion is used rather than sodium or potassium methylsulfinyl carbanion. This reagent gives

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