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937347

Sigma-Aldrich

(AdMPhos)PdCl2

Synonym(s):

1,1′-Bis(di-1-adamantylphosphino)ferrocene

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About This Item

Empirical Formula (Hill Notation):
C50H68Cl2FeP2Pd
Molecular Weight:
964.19
UNSPSC Code:
12352142
NACRES:
NA.21

form

powder

Quality Level

100

reaction suitability

reaction type: Cross Couplings

color

brown

functional group

phosphine

SMILES string

Cl[Pd]([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)([P](c8cccc8)(C9%10C[C@H]%11C[C@H](C[C@H](C%11)C%10)C9)C%12%13C[C@H]%14C[C@H](C[C@H](C%14)C%13)C%12)Cl.[Fe]

General description

(AdMPhos)PdCl2 is a symmetrical ferrocene-based Pd-catalyst. Part of the MPhos series of diphosphino-ferrocene ligands bearing bulky adamantyl groups. (AdMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling.

Application

Murahashi-Feringa Coupling (Alkyl-Li)
Kumada-Corriu coupling (Alkyl-MgX)
Negishi coupling (Alkyl-ZnX)
Suzuki–Miyaura coupling (Alkyl-B(OR2))

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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