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902500

Sigma-Aldrich

SHT-263 Solarpur®

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Synonym(s):

N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine, Spiro-MeOTAD, Spiro-OMeTAD

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About This Item

Empirical Formula (Hill Notation):
C81H68N4O8
CAS Number:
207739-72-8
Molecular Weight:
1225.43
MDL number:
MFCD12022511
UNSPSC Code:
12352103
NACRES:
NA.23

Assay

≥99.9%

Quality Level

100

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤0.1% Residual solvent

mp

247 °C

greener alternative category

Enabling,

InChI

1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3

InChI key

XDXWNHPWWKGTKO-UHFFFAOYSA-N

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General description

Both SHT-263S and SHT-263 can be offered in bulk quantities.
SHT-263 Solarpur® is an organic spiro molecule that is used as a hole transporting material (HTM). Its properties include high stability, good solubility, and an amorphous structure. It is majorly used in the fabrication of high-performance solar cells.
We are committed to bringing you Greener Alternative Products,which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an enabling product used as a Hole Transport Material for high-performance solar cells and thus has been enhanced for energy efficiency. Click here for more information.

Application

SHT-263 Solarpur® is a spiro based hole transporting material (HTM) with a HOMO level of -5.2 eV and a LUMO level of -2.3 eV. It is mainly used in the fabrication of perovskite-based solar cell.

Legal Information

Solarpur is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN5130
MKCL1270
MKCJ0655

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G Grancini et al.
Nature communications, 8, 15684-15684 (2017-06-02)
Despite the impressive photovoltaic performances with power conversion efficiency beyond 22%, perovskite solar cells are poorly stable under operation, failing by far the market requirements. Various technological approaches have been proposed to overcome the instability problem, which, while delivering appreciable
New Metal- Free Porphyrins as Hole- Transporting Materials in Mesoporous Perovskite Solar Cells.
Sygkridou D, et al.
ChemistrySelect, 3(9), 2536-2541 (2018)
Air-exposure induced dopant redistribution and energy level shifts in spin-coated spiro-MeOTAD films
Hawash Z, et al.
Chemistry of Materials, 27(2), 562-569 (2015)
Unique hole transport layer of PCDTBT doped with PCPDTBT for perovskite solar cells
Pratyusha T, et al.
Materials Today: Proceedings, 4(7), 6820-6826 (2017)
Hairen Tan et al.
Science (New York, N.Y.), 355(6326), 722-726 (2017-02-06)
Planar perovskite solar cells (PSCs) made entirely via solution processing at low temperatures (<150°C) offer promise for simple manufacturing, compatibility with flexible substrates, and perovskite-based tandem devices. However, these PSCs require an electron-selective layer that performs well with similar processing.
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