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698717

Sigma-Aldrich

Polyoxyethanyl-α-tocopheryl sebacate

greener alternative

15 wt. % in H2O

Synonym(s):

PTS

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About This Item

CAS Number:
263015-34-5
UNSPSC Code:
12162002
NACRES:
NA.22

form

liquid

Quality Level

100

mol wt

~1,200

reaction suitability

reaction type: C-C Bond Formation

greener alternative product characteristics

Waste Prevention
Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

15 wt. % in H2O

greener alternative category

Aligned,

General description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase the catalytic efficiency and acts as an environmentally benign and sustainable amphiphile. Click here for more information.

Application

PTS: Amphiphile for Organic Synthesis in Water

Uses:
  • Provides an aqueous micellar environment for transition metal-catalyzed Heck coupling, cross metathesis and ring closing metathesis reactions
  • Surfactant for catalytic asymmetric Baeyer-Villiger oxidation in water using PtII catalysts and hydrogen peroxide
  • Orally active CoQ10 carrier for neuroprotection after stroke or cardiac arrest

Legal Information

Product of Zymes LLC sold under exclusive license to US and worldwide patents.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN9872
MKCL8988
MKCH9292
MKCB6039
MKBZ1035V

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Articles

Nok – Third-Generation Amphiphile for Cross-Coupling Chemistry in Water

Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.

Baeyer-Villiger Oxidation Reaction

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

Related Content

Lipshutz Group – Professor Product Portal

Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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