404926

Vanadium(V) oxytriisopropoxide

• Synonym(s): Triisopropoxyvanadium(V) oxide, VTIP, Vanadium(V) trisisopropoxide oxide
• Linear Formula: OV(OCH(CH₃)₂)₃
• CAS Number: 5588-84-1
• Molecular Weight: 244.20
• EC Number: 226-997-4
• MDL number: MFCD00015017
• UNSPSC Code: 12352103
• PubChem Substance ID: 24865281
• NACRES: NA.23

Properties

• form: liquid
• Quality Level: 200
• composition: V, 20.3-21.4% titration (by potassium permanganate)
• reaction suitability: core: vanadium; reagent type: catalyst
• refractive index: n20/D 1.479 (lit.)
• bp: 80-82 °C/2 mmHg (lit.)
• density: 1.035 g/mL at 25 °C (lit.)
• SMILES string: CC(C)O[V](=O)(OC(C)C)OC(C)C
• InChI: 1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3
• InChI key: DSGGJXAUQHKOGQ-UHFFFAOYSA-N

Description

Application

Asymmetric Transfer Hydrogenation

Vanadium(V) oxytriisopropoxide is a building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis. Vanadium (V) oxytriisopropoxide (VOTP) may be used directly as a V precursor to dope TiO₂ to form a high performance anode for lithium ion batteries.

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Warning
• Hazard Statements: H226,H315,H319,H335
• Precautionary Statements: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 113.0 °F - closed cup
• Flash Point(C): 45 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves