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368350

Sigma-Aldrich

Poly(9-vinylcarbazole)

average Mn 25,000-50,000

Synonym(s):

PVK

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About This Item

CAS Number:
25067-59-8
MDL number:
MFCD00134336
UNSPSC Code:
12352103
NACRES:
NA.23

mol wt

average Mn 25,000-50,000

Quality Level

100

mp

>300 °C

density

1.2 g/mL at 25 °C (lit.)

Orbital energy

HOMO 5.8 eV 
LUMO 2.2 eV 

OLED Device Performance

ITO/PEDOT:PSS/PVK/PFO:Ir(btpy)3 (5 wt%)/Ca

  • Color: red
  • Max. Luminance: 726.5 Cd/m2
  • Max. EQE: 2.32 %

ITO/PEDOT:PSS/PVK:FIr6 (10 wt%)/TPBI/CsF:Al
  • Color: blue
  • Max. Luminance: 13800 Cd/m2
  • Max. EQE: 1.98 %
  • Turn-On Voltage: 5.5 V

ITO/PEDOT:PSS/PVK:Ir(mppy)2 (6 wt%)/Bphen/LiF:Al
  • Color: green
  • Max. Luminance: 10000 Cd/m2
  • Max. EQE: 1.1 %
  • Turn-On Voltage: 3.8 V

Mw/Mn

~2

InChI

1S/C14H11N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h2-10H,1H2

InChI key

KKFHAJHLJHVUDM-UHFFFAOYSA-N

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General description

Poly(9-vinylcarbazole) (PVK) is a conjugated polymer with hydrophobic properties. PVK films have a glass transition temperature (Tg) of 200°C and are mainly used as hole transport materials for semiconductor application.

Application

PVK can be used for the synthesis of titanium oxide (TiO2) quantum dots fillers that find potential applications as donor-acceptor layers in polymeric solar cells. It may be used to functionalize carbon nanotubes (CNTs) and form conductive reinforcements on epoxy groups. Iridium composites may be surface modified by PVK for the fabrication of highly efficient organic light emitting devices.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ7862
MKCP8936
MKCM9734
MKCF1458
MKCF3735

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Use of poly (9-vinylcarbazole) as host material for iridium complexes in high-efficiency organic light-emitting devices.
Yang M and Tsutsui T
Japanese Journal of Applied Physics, 39(8A), L828-L828 (2000)
Efficient white polymer light-emitting diodes from single polymer exciplex electroluminescence.
Liang J, et al.
Journal of Material Chemistry C, 5(9), 2397-2403 (2017)
Noncovalent functionalization of carbon nanotube using poly (vinylcarbazole)-based compatibilizer for reinforcement and conductivity improvement in epoxy composite.
Liu R, et al.
Journal of Applied Polymer Science, 134(26), 199-206 (2017)
Poly (9-vinylcarbazole) as a hole transport material for efficient and stable inverted planar heterojunction perovskite solar cells.
Yang L, et al.
Solar Energy Materials and Solar Cells, 163, 210-217 (2017)
Thermally Cross-Linkable Hole-Transporting Materials for Improving Hole Injection in Multilayer Blue-Emitting Phosphorescent Polymer Light-Emitting Diodes
Liu, M. S.; et al.
Marcromolecules, 41, 9570-9580 (2008)
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