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282235

Sigma-Aldrich

Methylmagnesium bromide solution

1.4 M in THF: toluene (1:3)

Synonym(s):

Bromomethylmagnesium

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About This Item

Linear Formula:
CH3MgBr
CAS Number:
Molecular Weight:
119.24
Beilstein:
3535220
MDL number:
UNSPSC Code:
12352111
PubChem Substance ID:
NACRES:
NA.22

Pricing and availability is not currently available.

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

1.4 M in THF: toluene (1:3)

density

1.018 g/mL at 25 °C

SMILES string

C[Mg]Br

InChI

1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AVFUHBJCUUTGCD-UHFFFAOYSA-M

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This Item
153575515357221372061
manufacturer/tradename

USP

manufacturer/tradename

USP

manufacturer/tradename

USP

manufacturer/tradename

USP

format

neat

format

neat

format

neat

format

neat

application(s)

pharmaceutical (small molecule)

application(s)

pharmaceutical (small molecule)

application(s)

pharmaceutical (small molecule)

application(s)

pharmaceutical (small molecule)

API family

defatted powdered soy

API family

phosphatidylcholine

API family

phosphatidic acid

API family

lysophosphatidylcholine

storage temp.

-10 to -25°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

Application

Methylmagnesium bromide is generally used as a Grignard reagent for C-C bond formation by reacting with the carbonyl groups of aldehydes and ketones.[1]

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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