226475
Phenyl vinyl sulfide
97%
Synonym(s):
(Phenylthio)ethylene
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About This Item
Linear Formula:
C6H5SCH=CH2
CAS Number:
Molecular Weight:
136.21
Beilstein:
969970
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
liquid
refractive index
n20/D 1.599 (lit.)
bp
94-95 °C/25 mmHg (lit.)
density
1.042 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C=CSc1ccccc1
InChI
1S/C8H8S/c1-2-9-8-6-4-3-5-7-8/h2-7H,1H2
InChI key
GMPDOIGGGXSAPL-UHFFFAOYSA-N
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Application
Phenyl vinyl sulfide was used in the synthesis of 2-fluoropyridinyl-6-oxy- precursors.
Signal Word
Warning
Hazard Statements
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
114.8 °F - closed cup
Flash Point(C)
46 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Laurent Debien et al.
Organic letters, 15(24), 6250-6253 (2013-11-26)
2-Fluoropyridinyl-6-oxy- precursors derived from phenyl vinyl sulfide react with radicals generated from xanthates via an addition-elimination process to furnish the corresponding vinyl sulfides in good yields. This convergent method is operationally simple and enables a straightforward synthesis of the difficult
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