206555
4-Iodotoluene
99%
Synonym(s):
1-Iodo-4-methylbenzene
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About This Item
Linear Formula:
CH3C6H4I
CAS Number:
Molecular Weight:
218.03
Beilstein:
1903637
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
solid
bp
211.5 °C (lit.)
mp
33-35 °C (lit.)
SMILES string
Cc1ccc(I)cc1
InChI
1S/C7H7I/c1-6-2-4-7(8)5-3-6/h2-5H,1H3
InChI key
UDHAWRUAECEBHC-UHFFFAOYSA-N
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General description
4-Iodotoluene undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium. Cobalt-catalyzed coupling of 4-iodotoluene with thiophenols and alkanethiols has been investigated. Palladium/copper-catalyzed Sonogashira cross-coupling reaction of 4-iodotoluene with phenylacetylene has been studied.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
194.0 °F - closed cup
Flash Point(C)
90 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Wancheng Zhu et al.
Inorganic chemistry, 51(11), 6020-6031 (2012-05-16)
(Ni(1-x),Mg(x))(3)Si(2)O(5)(OH)(4) solid-solution nanotubes (NTs) with tunable compositions were hydrothermally synthesized by altering the molar ratio of Mg(2+) to Ni(2+). The as-synthesized NTs were loaded with sub-0.06 wt % palladium (Pd; ∼0.045 wt %) for Suzuki-Miyaura (SM) coupling reactions between iodobenzene
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The Journal of organic chemistry, 71(25), 9499-9502 (2006-12-02)
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Organic letters, 8(24), 5613-5616 (2006-11-17)
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