ALD00600

Zhu-Yu Auxiliary

98%

• Synonym(s): 1-Carboxy-1-methylethoxyammonium chloride, 2,2-Dimethyl aminooxyacetic, 2-(Aminooxy)-2-methylpropanoic acid hydrochloride
• Empirical Formula (Hill Notation): C₄H₁₀ClNO₃
• CAS Number: 89766-91-6
• Molecular Weight: 155.58
• MDL number: MFCD08063911
• UNSPSC Code: 12352101

Properties

• Assay: 98%
• form: powder or crystals
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• availability: available only in USA
• mp: 150-165 °C
• InChI: 1S/C4H9NO3.ClH/c1-4(2,8-5)3(6)7;/h5H2,1-2H3,(H,6,7);1H
• InChI key: ZJPZGAAOCIFBDI-UHFFFAOYSA-N

Description

Application

The Zhu-Yu Auxiliary was reported by Jin-Quan Yu′s lab to be an effective auxiliary for the Pd(II)-catalyzed ß-C(sp3)-H(hetero)arylation of ketones.

Other Notes

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via ß-C(sp3)-H Activation

Safety Information

• Pictograms: GHS02
• Signal Word: Danger
• Hazard Statements: H242
• Precautionary Statements: P210 - P234 - P235 - P240 - P370 + P378 - P403
• Hazard Classifications: Self-react. C
• Storage Class Code: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable